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Vinyl Acetate Monomer (VAM)
Overview
AS no. 108-05-4
EINECS no. 203-545-4
Molecular formula: C4H6O2
Synonyms: VAM, Vinyl Acetate, Ethenyl Acetate, Ethenyl Ethanoate, 1-Acetoxyethylene, Vinyl Acetate
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Chemical Identity

Chemical Formula: C4H6O2
IUPAC Name: Ethenyl ethanoate
CAS Number: 108-05-4
Molecular Weight: 86.09 g/mol
Structural Formula: CH3COOCH=CH2

Physical and Chemical Properties

Appearance: Colorless liquid
Odor: Sweet, fruity smell
Density: 0.93 g/cm³ at 20°C
Boiling Point: 72-73°C
Melting Point: -93°C
Flash Point: -8°C (closed cup)
Solubility:
Slightly soluble in water (2.5 g/100 mL at 20°C)
Fully miscible with most organic solvents like ethanol, acetone, and benzene

Technical Specifications

Items

Technical requirement

Best quality

First quality

Qualifier

Appearance

Colorless and transparent

Density(20),g/cm3

0.930~0.934

0.930~0.934

0.929~0.935

Free acid (as acetic acid),%

0.005

0.010

0.020

Aldehyde(as acetaldehyde),%

0.02

0.04

0.05

Dry residue,%

0.005

0.05

0.10

Water content,%

0.04

0.10

0.20

Activity (second) (frothing time), second

660

690

720

Color(platinum-cobalt scale)

5

10

15

Purity,% =

99.80

99.70

Boiling range (101.3kpa),C

71.0~73.5

71.0~73.5

71.0~73.5

Packaging and delivery

liquid vinyl acetate monomers 25kg/drum or 200kg/drum (blue plastic drum), and IBC drum with metal frame for UV curing monomers
Port Shanghai
Applications

VAM is a key monomer in the production of various polymers and copolymers, essential in multiple industries:
Polyvinyl Acetate (PVA):
A primary application of VAM, used in adhesives (e.g., wood glue), paints, coatings, and textile finishes.
Ethylene Vinyl Acetate (EVA):
Copolymerized with ethylene to produce EVA, which is flexible and durable.
Applications include footwear, solar encapsulants, and packaging films.
Polyvinyl Alcohol (PVOH):
Produced by hydrolyzing polyvinyl acetate.
Widely used in biodegradable films, water-soluble packaging, and industrial adhesives.
Coatings and Paints:
VAM is used in water-based emulsion paints, offering excellent adhesion, durability, and weather resistance.
Adhesives and Sealants:
VAM-based resins are key ingredients in pressure-sensitive adhesives and laminating adhesives.
Textile and Paper Industries:
Provides finishes to textiles and coatings for glossy papers.

Health, Safety, and Environmental Considerations

Health Hazards:
Flammable liquid and vapor.
Can cause irritation to eyes, skin, and respiratory tract.
Prolonged exposure may affect the central nervous system.
Storage and Handling:
Store in cool, dry, and well-ventilated areas away from heat and ignition sources.
Use explosion-proof equipment.
Environmental Impact:
Classified as a volatile organic compound (VOC).
Requires controlled usage to minimize environmental emissions.


Vinyl Acetate Monomer (VAM) is an indispensable material in modern industries, serving as a cornerstone in the production of polymers and resins that enhance the quality, performance, and sustainability of everyday products. Its versatility and adaptability make it a vital component in industries such as construction, packaging, automotive, and textiles. With growing innovation and demand for eco-friendly solutions, VAM's role in material science is set to expand further.

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