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Vinyl Acetate
Overview
Vinyl acetate, also known as vinyl acetic ester, is an organic compound with the chemical formula C4H6O2. It is a colorless liquid with a sweet, fruity smell. This compound is widely used as a monomer in the production of polyvinyl acetate and other polymers, which are essential in adhesives, paints, coatings, and textile finishes. Vinyl acetate is also used as an intermediate in the production of various chemicals and materials, contributing to industries like construction, packaging, and consumer goods.
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Chemical Identity

Chemical Formula: C4H6O2
IUPAC Name: Ethenyl ethanoate
CAS Number: 108-05-4
Molecular Structure: CH3COOCH=CH2

Physical and Chemical Properties

Appearance: Colorless liquid
Odor: Sweet, fruity odor
Density: 0.93 g/cm³ at 20°C
Boiling Point: 72-73°C
Flash Point: -8°C (closed cup)
Solubility: Slightly soluble in water; highly miscible with organic solvents like ethanol, acetone, and benzene.

Technical Specifications

Items

Technical requirement

Best quality

First quality

Qualifier

Appearance

Colorless and transparent

Density(20),g/cm3

0.930~0.934

0.930~0.934

0.929~0.935

Free acid (as acetic acid),%

0.005

0.010

0.020

Aldehyde(as acetaldehyde),%

0.02

0.04

0.05

Dry residue,%

0.005

0.05

0.10

Water content,%

0.04

0.10

0.20

Activity (second) (frothing time), second

660

690

720

Color(platinum-cobalt scale)

5

10

15

Purity,% =

99.80

99.70

Boiling range (101.3kpa),C

71.0~73.5

71.0~73.5

71.0~73.5

Packing & Storage

Storage Close, protect from light, ventilated and dry, cool, do not mix storage.
Shipping Equipped with appropriate varieties and quantities of fire-fighting equipment.
Production Methods

Vinyl acetate is primarily produced through the reaction of ethylene, acetic acid, and oxygen in the presence of a palladium-based catalyst. This process is known as oxidative acetoxylation:
C2H4 + CH3COOH + 12O2 → CH3COOCH = CH2 + H2O
C2H4 + CH3COOH + 21O2 → CH3COOCH = CH2 + H2O

Applications

Polyvinyl Acetate (PVA):
Used in adhesives (e.g., wood glues), paints, coatings, and textile finishes.
PVA is a precursor for polyvinyl alcohol (PVOH), which finds use in paper coatings and films.
Ethylene Vinyl Acetate (EVA):
A copolymer of ethylene and vinyl acetate, widely applied in footwear, flexible films, foam sheets, and solar encapsulants.
The vinyl acetate content in EVA enhances elasticity, transparency, and impact resistance.
Polyvinyl Alcohol (PVOH):
Derived from polyvinyl acetate through hydrolysis.
Widely used in biodegradable films, water-soluble packaging, and adhesives.
Intermediate in Chemical Synthesis:
Vinyl acetate acts as a monomer in the synthesis of various resins, coatings, and polymers.
Other Uses:
Paper coatings for glossy finishes
Laminates in furniture and packaging
Water-based paints and emulsions
Industrial Importance:
Vinyl acetate is a vital monomer in the global polymer industry due to its versatility, cost-effectiveness, and ability to enhance material performance. It is heavily used in adhesives, construction materials, and consumer goods.

Safety and Handling

Hazards:
Flammable liquid and vapor (Category 2).
Exposure can cause irritation to eyes, skin, and respiratory tract.
Long-term exposure may have health effects; proper precautions are required.
Storage:
Store in cool, dry, and well-ventilated areas away from heat sources.
Use explosion-proof equipment for handling.
Environmental Impact:
Vinyl acetate is classified as a volatile organic compound (VOC) and can contribute to air pollution. However, when used and disposed of correctly, its environmental risks can be minimized. Industries are increasingly adopting sustainable methods to produce and utilize vinyl acetate.

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